Absorption in the near-ultraviolet wing of the Kr₂F*(410 nm) band

An intracavity laser technique has been used to study the absorption of electron-beam pumped Ne/Kr/F2gas mixtures (196 and 300 K) in the "blue wing" of the Kr2F emission continuum. The experiments were conducted at 358 nm using theυ' = 0 → υ" = 1transition of the N2(C → B) laser. Comparing the results with the predictions of a computer model, the species primarily responsible for absorption have been identified as Ne+2, Kr+2, and Kr2F*. The photoabsorption cross sections for Ne+2and Kr2F (Kr+2F-) at 358 nm have been estimated to be8.1 · 10⁻¹⁹and5.4 · 10⁻¹⁸cm2, respectively. The Kr2F* absorption cross section is roughly 20 percent of that reported for Kr+2at the same wavelength. The fluorescence efficiency of Kr2F* ine-beam excited 94.93 percent Ne/5 percent Kr/0.07 percent F2(Pₜₒₜₐₗ = 4000torr) gas mixtures has been found to be a factor of 2.8 higher than that of the N2(C → B) band in Ar/5 percent N2mixtures. Also, the rate constant for quenching of Kr2F* by F2was measured to be(4.1 ± 0.5) · 10⁻¹⁰cm3. s-1at 300 K and(3.0 ± 0.5) · 10⁻¹⁰cm2. s-1at 196 K.