Homogeneous Esterification of Cellulose in the Mixture N-Butylpyridinium Chloride/Dimethylsulfoxide

The present study deals with the homogeneous acylation of cellulose with p -nitrobenzoyl chloride in a reaction medium composed of a mixture of 1-butylpyridinium chloride and dimethylsulfoxide (BPyCl/DMSO), in the presence of different bases and under mild conditions. The preparation of cellulose p -nitrobenzoate depending on the reaction conditions, the influences of reaction parameters such as the base type, and the types of cellulose (kraft and microcrystalline) on the products were investigated. Cellulose p -nitrobenzoate with a degree of substitution (DS) in the range from 0.12 to 1.5 was accessible, with a low excess of reagent and for a short reaction time. The cellulose esters were characterized by 1 H-NMR, 13 C NMR, and FT-IR spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and solubility tests.