Conjugate addition of 4-tert-butylbenzenethiol to pseudorotaxane having terminal α,β-unsaturated ester group under radical condition afforded the corresponding aryl sulfide-capped rotaxane, while conjugate addition of sodium 4-tert-butylbenzenesulfinate under acidic condition also yielded aryl sulfone-capped rotaxane.
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Takata et al. (1999) studied this question.
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