A direct consequence of quantization of gravity would be the existence of gravitons. Therefore, spontaneous transition of an atom from an excited state to a lower-lying energy state accompanied with the emission of a graviton is expected. In this paper, we take the gravitons emitted by hydrogen and helium in the Universe after recombination as a possible source of high frequency background gravitational waves, and calculate the energy density spectrum. Explicit calculations show that the most prominent contribution comes from the $$3d-1s$$ 3d-1s transition of singly ionized helium He⁺ He+ , which gives a peak in frequency at ~ 10¹³ ∼1013 Hz. Although the corresponding energy density is too small to be detected even with state-of-the-art technology today, we believe that the spontaneous emission of He⁺ He+ is a natural source of high frequency gravitational waves, since it is a direct consequence if we accept that the basic quantum principles we are already familiar with apply as well to a quantum theory of gravity.
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