Cross-Linked Network Polymer Electrolytes Based on a Polysiloxane Backbone with Oligo(oxyethylene) Side Chains:  Synthesis and Conductivity

A novel cross-linked siloxane-based solid polymer network has been synthesized by the hydrosilylation of polymethylhydrosiloxane (PMHS) partly substituted with oligo(ethylene glycol) methyl ether side groups and a α,ω-diallyl poly(ethylene glycol) cross-linking reagent. The ionic conductivities of the networks doped with LiTFSI are high at ambient temperature (σ = 1.33 × 10 -4 S cm -1 at the optimum LiTFSI concentration EO/Li + = 20:1). The temperature dependence of the conductivity followed the VTF form, indicating that polymer segmental motion assists the ion transport in the solid networks.