A prototype photothermal procedure: Alkylsiloxane monolayers on surface-oxidized silicon substrates are processed in gaseous bromine using a focused Ar+-laser operated at λ=514 nm. Monolayer bromination remains confined to a micrometer-sized reaction zone, where laser irradiation results in a local temperature rise (see figure).
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Klingebiel et al. (2009) studied this question.
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