Progress in the Synthesis of Nanocrystalline BaTiO 3 Powders for MLCC

Future improvements in the development of highly volume‐efficient multilayer ceramic capacitors (MLCC) require manufacturing processes that allow for a reduced dielectric thickness well below 1 μm. Obviously, such thin dielectric layers can only be produced if nanosized dielectric powders are applied and deposited by techniques more advanced than tape casting and screen printing. These processes require high‐purity, homogeneous, weakly agglomerated ultrafine powders. Over the past few years, significant progress has been made in the synthesis of nanocrystalline BaTiO 3 ‐based powders for use in MLCC. The present review article aims to summarize the present state of the art with respect to some of the technically and industrially most relevant preparation routes, including methods based on solid‐state reactions and, more importantly, solution‐based approaches.