The electrochemical method of the introduction of α-acetoxy or α-methoxy group on a ketone was applied to accomplish the 1,2-carbonyl transposition in ketones. The acid-catalyzed reaction of β-acetoxy or β-methoxy alcohols prepared by the reduction or Grignard reaction of the α-acetoxy or α-methoxy ketones gave the 1,2-carbonyl transposed ketones.
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Shono et al. (1976) studied this question.
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