The kinetics of the NCN + NO reaction has been studied using laser-induced fluorescence spectroscopy over the temperature range 298−573 K to measure total rate constants and time-resolved infrared diode laser spectroscopy as a probe for possible products. The reaction has a rate constant of k (NCN + NO) = (2.88 ± 0.2) × 10 -13 cm 3 molecule -1 s -1 at 298 K and low (∼3 Torr) total pressure. The rate constant displays both a temperature as well as a pressure dependence, indicating that adduct formation is a major product channel. Only very small amounts of other products were detected. Upper limits for the low-pressure rate constants of NCN + O 2, C 2 H 4, and NO 2 were also obtained.
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Baren et al. (2002) studied this question.
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