Highly vibrationally excited NO(v = 1–10) has been created by irradiation of N2/trace O2 mixtures with 36 keV electrons. The resulting spectrally-resolved time histories of the NO fundamental vibration/rotation band have been analyzed to determine the room temperature rate constants for the processes NO(v)+O2→NO(v−1)+O2, v = 1–7. The rate constants increase monotonically with v.
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Green et al. (1982) studied this question.
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