Abstract : Supported Pd nanoparticles catalyzed the reductive cycloisomerization of diynes to give 1,3‐dienes, and subsequent intermolecular [4+2] cycloaddition with dienophiles led to cyclohexene derivatives. Various diynes and dienophiles participated in the one‐pot reaction to give the corresponding products in good to high yields. Al 2 O 3 ‐supported Pd catalysts were highly tolerant toward air and reusable.
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Miura et al. (2019) studied this question.
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