April 6, 2004Journal of the American Chemical Society

Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex

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RDReto DortaThe University of Western Australia ESEdwin D. StevensBowling Green State University SNSteven P. NolanRutgers, The State University of New Jersey

Abstract

The solvent-dependent interaction of ItBu with a Rh(I)-olefin complex leads to the isolation of two precursors en route to a unique double cyclometalation process. Abstraction of the chloride ligand from the resulting complex enables the isolation of a "bare" 14-electron Rh(III) complex.

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Dorta et al. (2004) studied this question.

synapsesocial.com/papers/6a88595917733fb165eb351a https://doi.org/10.1021/ja049545+

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Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex

Abstract

Discussion

Cite This Study

Double C−H Activation in a Rh−NHC Complex Leading to the Isolation of a 14-Electron Rh(III) Complex

Abstract

Discussion

Cite This Study

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