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The structure of cones of positive and k-positive maps acting on a finite-dimensional Hilbert space is investigated. Special emphasis is given to their duality relations to the sets of superpositive and k-superpositive maps. We characterize k-positive and k-superpositive maps with regard to their properties under taking compositions. A number of results obtained for maps are also rephrased for the corresponding cones of block positive, k-block positive, separable, and k-entangled operators due to the Jamiołkowski–Choi isomorphism. Generalizations to a situation where no such simple isomorphism is available are also made, employing the idea of mapping cones. As a side result to our discussion, we show that extreme entanglement witnesses, which are optimal, should be of special interest in entanglement studies.
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