Strong enhancement of forbidden atomic transitions using plasmonic nanostructures

We investigate the mediation of symmetry-forbidden atomic transitions using plasmonic nanostructures. We show that the excitation of the electric dipole-forbidden, quadrupole-allowed 60.16em0ex²S1/2-50.16em0ex²D5/2 transition in cesium may be enhanced by more than 6 orders of magnitude in the intense, inhomogeneous near field of a plasmonic nanoantenna. Using optical reciprocity, the enhancement can be understood to apply to spontaneous emission as well, allowing the fast and efficient optical detection of excited atoms.