The polymer [Ni2(C4N2H3S)4] n with excellent electrical conductivity and ferromagnetic interaction between the nickel(II) centers has been prepared by the hydrothermal reaction of Ni(O2CMe)2 with pyrimidine-2-thiol in DMF–H2O; X-ray diffraction shows that the polymer possesses a lamellar structure formed from the conjunction system of pyrimidine rings and Ni(II) centers.
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Zhao et al. (2001) studied this question.
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