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Mass distribution and molecular flux during sublimation of several functional organic compounds such as tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ), Copper-phthalocyanine and fullerene in ultrahigh vacuum are directly measured using a high-performance quadrupole mass spectrometer. It was confirmed that molecules in a complexed form sublime as individual molecules from a Knudsen cell (K-cell). The dependence of evaporation rate on the temperature of the K-cell was numerically calibrated for the first time.
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Yase et al. (1995) studied this question.
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