The aurophilicity of sulfur and the bridging of gold(I) centers by bis(diphenylphosphanyl)-n-propylamine (PNP) ligands result in the self-assembly of the highly soluble high-nuclearity propeller-shaped complex [Au10(μ-PNP)4(μ3-S)4](PF6)2 (see picture), which exhibits long-lived luminescence in the microsecond range.
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Yam et al. (2000) studied this question.
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