July 1, 1977Australian Journal of Chemistry

Cyclopentadienyl-ruthenium and -osmium chemistry. IV. Convenient high-yield synthesis of some cyclopentadienyl ruthenium or osmium tertiary phosphine halide complexes

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Abstract

High-yield one-pot syntheses of RuCl(PR3)2(η-C5H5) (R = Ph or p-MeC6H4) and OsBr(PPh3)2- (η-C5H5) from ruthenium or osmium halides, the tertiary phosphine and cyclopentadiene are described.

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Cite This Study

Bruce et al. (1977) studied this question.

synapsesocial.com/papers/6a89155fab71709247a2b119 https://doi.org/10.1071/ch9771601

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Abstract

High-yield one-pot syntheses of RuCl(PR3)2(η-C5H5) (R = Ph or p-MeC6H4) and OsBr(PPh3)2- (η-C5H5) from ruthenium or osmium halides, the tertiary phosphine and cyclopentadiene are described.