The reaction of (trisubstituted cyclopentadienyl)tris(acetonitrile)ruthenium complexes, [Cp′Ru(CH3CN)3][PF6], with prochiral trisubstituted arenes gave planar-chiral [Cp′Ru(arene)][PF6] complexes with a diastereoselectivity up to 46% d.e.
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Komatsuzaki et al. (1998) studied this question.
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