The band structure of gold for energies far above the Fermi level has been calculated using the relativistic augmented-plane-wave method. The calculated f-band edge (Γ₆^-) lies 15.6 eV above the Fermi level is agreement with recent photoemission work. The band model is applied to interpret temperature-modulated reflectance data covering photon energies up to 35 eV.
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N. E. Christensen (1976) studied this question.
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