The transfer constant for the butadiene‐polybutadiene system at 50°C. has been calculated from data obtained from a graft polymerization study of that system. This constant (K = 1.1 × 10−3) has been used to calculate that polybutadiene prepared in an emulsion system at 50°C. contains an average of one branch for every 800 monomer units.
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Robert A. Hayes (1954) studied this question.
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