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The cooperative effect of pyridine catalysis with photoenhanced electrochemical reduction by CdTe/FTO of CO2 is explored. The enhancement of overall formic acid production and high faradaic efficiency is due to the increased photocurrent of CdTe/FTO upon irradiation and the decrease in activation barrier due to the formation of a pyridine–CO2 intermediate.
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Jeon et al. (2013) studied this question.
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