A novel dimeric penta-coordinated ion cavity of [Li + ] 2 [12-crown-4-ether] 3 has been formed in the highly conducting Ni(dmit) 2 salt. This salt showed a room-temperature conductivity of 30 S cm -1 and exhibited a semiconductor–semiconductor phase transition on the application of pressure or on lowering the temperature.
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Akutagawa et al. (1997) studied this question.
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