Single crystals of KN3 doped with KNO2 and KNO3 were irradiated with ultraviolet light and x rays. EPR investigations of the paramagnetic centers stable at room temperature indicate that NO2− is the precursor for the NO2 and NO2−− centers observed, and that NO3− is the precursor for the NO2−− center only.
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Fuller et al. (1972) studied this question.
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