The increase in the standard partial molar volume of a symmetrical electrolyte on ion-pairing, ΔV∞, calculated from the experimental association constant at ambient pressure, the isothermal compressibility, the dielectric constant of the solvent and its pressure coefficient, is as good a measure of this quantity as values calculated from more elaborate experimental procedures, such as the pressure coefficient of the association constant or high precision density determinations in dilute solutions.
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Yizhak Marcus (1983) studied this question.
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