An unexplored family of polyoxometalates has evolved through the synthesis and structural characterization of the first examples of MoV sulfite heteropolyanions. The dodecanuclear molybdenum(V) sulfite exhibits a unique structural motif among polyoxometalates (see picture; gray polyhedra represent MoVO6 octahedral units, black, white, and gray balls are sulfur, oxygen, and nitrogen atoms, respectively).
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Manos et al. (2002) studied this question.