Lanthanoid chlorides formed the 1:1 complexes with triethylene glycol, tetraethylene glycol, pentaethylene glycol, tetraglyme, and pentaglyme. All the complexes were deliquescent. The yield of the solid complex with tetraethylene glycol decreased with the increase of the atomic number of the lanthanoid.
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Hirashima et al. (1983) studied this question.
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