The kinetics of graft copolymerization of polyacrylonitrile (PAN) onto nylon 6/nylon 66 and the simultaneous homopolymerization initiated by potassium peroxomonosulfate (PMS)–ascorbic acid (H2A) redox systems were studied separately. Various kinetics parameters were evaluated and analyzed to have a comparison among the systems. The occurrence of simultaneous homopolymerization was evident through rate parameters. When the backbone was changed, the following order was observed for grafting efficiency: polyester (PET) > nylon 6 ≳ nylon 66.
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Gopalan et al. (1995) studied this question.
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