The kinetics of graft copolymerization of polyacrylonitrile (PAN) onto polyester (PET) and the simultaneous homopolymerization initiated by the potassium penoxomonosulfate (PMS)–ascorbic acid (H2A) redox system were studied separately. Results on the graft copolymerization was adequately explained by a mechanism which also accounts for the reason for simultaneous homopolymerization. The observed homopolymerization results agreed with the proposal. Kinetic chain‐length measurements on the graft copolymer and homopolymerization were used to evaluate the kinetic parameters.
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Gopalan et al. (1995) studied this question.
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