Annelated pentafulvenes 2, 10, 13, and 14 are efficiently accessible by a palladium‐catalyzed domino coupling process of aryl substituted vinylic bromides 1, 9, 11, and 12, 5‐Membered palladacycles 3 are discussed as key intermediates.
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Dyker et al. (1996) studied this question.
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