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Reactivity ratios for the copolymerisation of vinyl acetate with methyl acrylate have been determined in bulk at 60°C for conversions smaller than 1% using proton magnetic resonance spectroscopy. The values (rma = 6.3 ± 0.4; rva = 0.031 ± 0.006) thus obtained were compared with the values obtained by other workers using different analytical techniques. The present method appears to be extremely simple and accurate.
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Kulkarni et al. (1970) studied this question.
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