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January 1, 2003Chemical Communications

A phenolysis route to a new type of octanuclear iron( iii ) wheel: [Fe 8 (OH) 4 (OPh) 8 (O 2 CBu t ) 12 ]

C. Cañada-Vilalta Maren Pink George Christou

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Abstract

Alcoholysis of [Fe6O2(OH)2(O2CBut)10(hep)2] (1) affords ferric wheels of different nuclearities: methanol yields [Fe10(OMe)20(O2CBut)10], whereas phenol gives the structurally unprecedented wheel [Fe8(OH)4(OPh)8(O2CBut)12], and the first to contain phenoxide.

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Cañada-Vilalta et al. (2003) studied this question.

synapsesocial.com/papers/6a893dcfb1e5d05ea8ec648f https://doi.org/10.1039/b301792c

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