In this paper, a study of simple organic/inorganic compounds by 15N and 13C CP MAS NMR using a selective sequence (Inversion Recovery Cross Polarization, IRCP) is presented. Such a sequence allows a precise insight in the CP dynamic of various 15NHx (x = 0 → 4) sites. It allows also the selection of the different NMR lines according to the number of directly bonded protons. This technique appears extremely useful for the study of inorganic polymerisation, starting from protonated precursors (borazines) and leading to non-protonated boron nitride (BN) phases.
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Bonhomme et al. (1995) studied this question.
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