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October 6, 2011Angewandte Chemie

A Hemin/G‐Quadruplex Acts as an NADH Oxidase and NADH Peroxidase Mimicking DNAzyme

Eyal Golub Ronit Freeman Itamar Willner

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Abstract

Enzym-Imitator: Ein DNAzym aus Hämin und einem G-Quadruplex imitiert die Aktivitäten von NADH-Oxidase unter aeroben Bedingungen und von NADH-Peroxidase unter anaeroben Bedingungen. Über diese biokatalytische Aktivität hinaus ist der Hämin-G-Quadruplex-Komplex in der Lage, den wichtigen biologischen Cofaktor NAD+ in beiden Zyklen zu regenerieren (siehe Bild).

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Golub et al. (2011) studied this question.

synapsesocial.com/papers/6a8955832c543859dc621b8e https://doi.org/10.1002/ange.201103853

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