Synthesis of Non-spherical LiNi 0.88 Co 0.09 Al 0.03 O 2 Cathode Material for Lithium-Ion Batteries

High-nickel-content NCA [LiNi 0.88 Co 0.09 Al 0.03 ] cathode material with non-spherical morphology that consisted of individual primary particles was synthesized at different temperatures. Optimized non-spherical NCA with a mean particle size of 3 μm is compared to conventional spherical NCA [LiNi 0.88 Co 0.09 Al 0.03 ] in terms of structural, electrochemical, and thermal stabilities. Non-spherical NCA demonstrates superior cycle performance at both 25 and 45 °C. Non-spherical NCA demonstrates superior structural stability with suppressed phase transition from H2 to H3 and anisotropic lattice distortion upon cycling. Electrochemical impedance of non-spherical NCA remained at the same level after 50 cycles, which indicates better structural and electrochemical stabilities. Non-spherical NCA exhibits a higher onset temperature of the exothermic reaction and lower total reaction heat, indicating better thermal stability. Capacity retention of pouch-type cells with non-spherical NCA as the cathode is greater than 91% after 1000 cycles, which shows great potential in the application for a high-energy-density lithium-ion battery for electric vehicles.