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Rate constants have been determined at (298 ± 4) K for the reactions: equation image and the relaxation processes: equation image Time‐resolved HF(1,0) emission was observed following the photolysis of F2 with pulses from an excimer laser operating on XeCl (λ = 308 nm). Analysis of the emission traces gave first‐order constants for reaction and relaxation, and their dependence on [H2O] and [HCN] yielded:
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Frost et al. (1986) studied this question.
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