Nascent product vibrational state distributions of ion–molecule reactions: The H+F−→HF(v)+e− associative detachment reaction

The nascent product vibrational state distribution is obtained for the thermal energy associative detachment reaction H+F−→HF(v?5)+e−, ΔH = −57.0 kcal/mol. The relative vibrational populations are as follows: Nv = 10 = 0.00±0.06; Nv = 20 = 0.23±0.04; Nv = 30 = 0.27±0.03; Nv = 40 = 0.29±0.03; and Nv = 50 = 0.21±0.03. Arguments are presented that suggest that Nv = 00 = 0. The average fraction of the total energy deposited in product vibration is