The interfacial grafting between the glassy polystyrene matrix and the rubber-like par ticle phase (gel phase) of High Impact Polystyrene (HIPS) is known to be important to the fracture toughness of the material [1]. A simple quantitative model is developed to determine interfacial grafting from the observed shifts between the glass transition temperature of pure matrix polystyrene and three commercial types of HIPS.
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Theocaris et al. (1988) studied this question.
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