(Triorganosilyl)pinacolboranes were prepared by reaction of triorganosilyllithium reagents with pinacolborane or isopropoxypinacolborane in high yield. The reaction also is applicable to synthesis of 2-(triorganosilyl)-4,4,6-trimethyl-1,3,2-dioxaborinane. A new germylborane derivative was similarly prepared from the corresponding germyllithium.
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Suginome et al. (2000) studied this question.
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