Run of the 'mill: An inorganic support (KF-Al2O3) was used to generate the base in situ for Suzuki reactions carried out using mechanochemical treatment in a ball mill. Various aryl halides were tested in the Pd-catalyzed coupling reaction with phenylboronic acid and KF-Al2O3. The best results were obtained with aryl bromides.
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Schneider et al. (2008) studied this question.
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