Angle Resolved Photoemission and Electronic Band Structure of MoS2

Angle‐resolved photoemission measurements are performed on the layer compound MoS2 at 21.2 and 40.8 eV excitation energies. It is shown the applicability of the E(k∥︁) method in the framework of a non‐direct transition regime. An experimental band scheme is proposed. Good agreement with band structure calculations is found except for some of them in the relative position of the d and p upper valence bands, which is here clearly ascertained.