Coisotactic parameters of two steps in a propagating process, one from styrene (St) unit to methyl methacrylate (MMA) unit and the other from MMA unit to St unit, were experimentally determined in alternating copolymerization of MMA with St under the copolymerization conditions giving highly coheterotactic poly(MMA-alt-St). The former step resulted in highly syndiotactic addition and the latter, in highly isotactic addition.
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Gotoh et al. (1991) studied this question.
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