Up to date, problems exist with the determination of kp values with respect to acrylates. The pulsed laser polymerization (PLP) data published so far only give consistent values of kp for temperatures below 30°C for acrylates. Recently, new insights in acrylate reactions seem to offer a plausible explanation for the failure of the pulsed initiation polymerization (PIP) experiment for acrylates that will be discussed here.
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Alex M. van Herk (2001) studied this question.
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