Spatially selective electrochemical deposition of a metal (Ni) into the ordered nanohole-array structure of anodic porous alumina was performed using a microelectrode. A patterned deposit consisting of fine Ni cylinders of 70 nm diameter was obtained in the hole-array structure with spatial resolution on the order of tens of micrometers, and its size was in good agreement with that of the microelectrode used as a tip.
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Masuda et al. (1998) studied this question.
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