Tales of the unexpected: The [70]fullerene chloride C70Cl16 resulted from the reaction of [70]fullerene with a mixture of Br2 and TiCl4. A single-crystal X-ray crystallographic study revealed the presence of two isomers of C70Cl16, both containing a belt of ten chlorine atoms around the equator and a skew pyramidal cap of six chlorine atoms on the pole of the C70Cl16 molecule (see picture).
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Troyanov et al. (2005) studied this question.
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