Message in a bottle: Alkaline hydrothermal treatment of lysozyme–silica hybrid particles leads to cagelike hollow aluminosilicates (CHAs) with vermiculate through-holes in the shell. Biomacromolecules can be transported inside the CHA through these holes and encapsulated within the confined inner space by crosslinking in a ship-in-bottle manner (see picture).
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Shiomi et al. (2008) studied this question.
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