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A semiempirical theory based on limited configuration interaction has been developed for the excimer luminescence of alternant hydrocarbons. The theory adequately accounts for (1) the energy of excimer luminescence (fluorescence and phosphorescence), (2) the linear relationship between the energies of the excimer fluorescence and the p band of the monomer, and (3) the near constancy of the energy difference between the monomer and excimer fluorescence.
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Chandra et al. (1968) studied this question.
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