This feature article highlights our recent work on oligoarene-type catalysts. We developed a synthetic method for multifunctionalized oligoarenes using a repetitive two-step strategy. The method was then applied to the preparation of oligoarene-type phosphines, which were used for palladium-catalyzed cross-coupling of halobenzenes with Grignard reagents.
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Manabe et al. (2008) studied this question.
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