No studies have been conducted to evaluate the potassium (K) quantity‐intensity (Q/I) relationships that exist in eastern South Dakota soils and how that may affect K fertility interpretations. The objectives of this study were to i) evaluate the K status of smectite‐dominant soils through quantity‐intensity relationships and (ii) relate the findings to current research on soil K release and plant availability. Soil and plant tissue samples were collected from eight different corn production fields across east‐central South Dakota. Samples were collected from areas where corn plants did or did not exhibit K deficiency symptoms. Quantity‐intensity plots were developed and used to derive the typical Q/I parameters. Little difference existed in Q/I parameters and the form of Q/I plots among field sites. The ARe K and ΔK0 values ranged from 0.0013 to 0.0113, and −0.47 to 0.18 cmolc kg−1, respectively, and most sites were considered K insufficient. The predominant phyllosilicate present in the clay‐sized fraction was montmorillonite with an estimated 17% tetrahedral charge. These soils would not be expected to contribute much plant‐available, nonexchangeable K and would be in need of frequent K fertilization. Presumably, these and similar soils, upon K exhaustion, rely heavily on K released from K‐bearing silt‐sized particles and may be highly dependent on surface‐controlled dissolution processes for labile K replenishment. Additional research needs to be conducted concerning the release kinetics of K from K‐bearing minerals of these soils.
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Schindler et al. (2005) studied this question.
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