By following a strategy introduced in previous works, quantum extensions of the classical electron-phonon scattering operator are deduced from first principles. These quantum collision operators satisfy a quantum H-theorem and relax towards quantum equilibria. Then, under an assumption of dominant elastic interactions, a hierarchy of quantum spherical harmonic expansion (SHE) models is derived by a diffusive approximation of collisional Wigner equations. These models are proven entropic and their expansions into powers of the reduced Planck constant ℏ are calculated, leading to ℏ2 corrections for the classical SHE model.
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Bourgade et al. (2006) studied this question.
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